Scientists have developed an innovative approach to improve all-solid-state lithium batteries. This new method involves using a unique material that eliminates the need for extra additives, enhancing both the battery’s energy density and its lifespan. The new material shows impressive performance, allowing the batteries to operate for over 20,000 cycles with high energy efficiency.
A new strategy for all-solid-state lithium batteries enhances energy density and extends lifespan by using a special material that removes the need for additional additives. This advancement promises over 20,000 cycles of efficient operation, marking a significant step forward in battery technology.
An innovative cathode homogenization strategy for all-solid-state lithium batteries (ASLBs) has been introduced by researchers at the Qingdao Institute of Bioenergy and Bioprocess Technology (QIBEBT) of the Chinese Academy of Sciences, along with collaborators from leading international institutions.
This new approach, detailed in their paper published today (July 31) in Nature Energy, significantly improves the cycle life and energy density of ASLBs, representing an important advancement in energy storage technology.
Challenges in Current ASLBs
Current ASLBs face challenges due to heterogeneous composite cathodes, which require electrochemically inactive additives to enhance conduction. These additives, while necessary, reduce the batteries’ energy density and cycle life due to their incompatibility with the layered oxide cathodes, which undergo substantial volume changes during operation.
Researchers have developed a solution: a cathode homogenization strategy utilizing a zero-strain material, Li1.75Ti2(Ge0.25P0.75S3.8Se0.2)3 (LTG0.25PSSe0.2). This material exhibits excellent mixed ionic and electronic conductivity, ensuring efficient charge transport throughout the (dis)charge process without the need for additional conductive additives.
The LTG0.25PSSe0.2 material shows impressive performance metrics, including a specific capacity of 250 mAh g–1 and minimal volume change of just 1.2%. A homogeneous cathode made entirely of LTG0.25PSSe0.2 enables room-temperature ASLBs to achieve over 20,000 cycles of stable operation and a high energy density of 390 Wh kg−1 at the cell level.
Schematic illustration of cathode microstructure evolution during charging. (a) Conventional heterogeneous composite cathode and (b) the proposed homogeneous cathode with efficient mixed conduction. Credit: QIBEBT
Expert Insights on the New Approach
“Our cathode homogenization strategy challenges the conventional heterogeneous cathode design,” said Dr. Longfei Cui, co-first author of the study from Solid Energy System Technology Center (SERGY) at QIBEBT. “By eliminating the need for inactive additives, we enhance energy density and extend the battery’s cycle life.”
“This approach is a game-changer for ASLBs,” remarked Dr. Shu Zhang, co-first author of the study from SERGY. “The combination of high energy density and extended cycle life opens up new possibilities for the future of energy storage.”
Prof. Jiangwei Ju, co-corresponding author of the study from SERGY, added, “The material’s stability and performance metrics are impressive, making it a strong candidate for commercial applications in electric vehicles and large-scale energy storage systems.”
This advancement is supported by extensive testing and theoretical calculations. These analyses confirm the electrochemical and mechanical stability of the homogeneous cathodes, showing no adverse chemical reactions or significant resistance increases after prolonged cycling.
Broader Implications for Energy Storage
Beyond ASLBs, other battery types, including solid-state sodium batteries, lithium-ion batteries, lithium-sulfur batteries, sodium-ion batteries, and fuel cells, also face challenges with heterogeneous electrodes. These systems often suffer from mechanochemical and electrochemical incompatibilities, creating significant bottlenecks and degrading overall battery performance.
“The commercialization potential for high-energy-density ASLBs is now more achievable,” added Prof. Guanglei Cui, head of SERGY. “Our universal strategy for designing multifunctional homogeneous cathodes can overcome the energy, power, and lifespan barriers in energy storage, paving the way for real-world applications.”
Significant Milestone in Battery Technology
By addressing key challenges in ASLBs, this strategy sets a foundation for future innovations in energy storage technology. The team plans to further explore the scalability of the LTG0.25PSSe0.2 material and its integration into practical battery systems.
This work represents a significant milestone in battery technology and offers a promising outlook for future advancements. The team’s innovative approach is expected to influence future research and development in the field of energy storage, providing a strong foundation for the next generation of high-performance batteries.
Reference: “A cathode homogenization strategy for enabling long-cycle-life all-solid-state lithium batteries” 31 July 2024, Nature Energy. DOI: 10.1038/s41560-024-01596-6
Source: SciTechDaily