Novel color photography using a high-efficiency probe can super-focus white light into a 6-nanometer spot for nanoscale color imaging.

Scientists have developed new materials for next-generation electronics so tiny that they are not only indistinguishable when closely packed, but they also don’t reflect enough light to show fine details, such as colors, with even the most powerful optical microscopes. Under an optical microscope, carbon nanotubes, for example, look grayish. The inability to distinguish fine details and differences between individual pieces of nanomaterials makes it hard for scientists to study their unique properties and discover ways to perfect them for industrial use.

In a new report in Nature Communications, researchers from UC Riverside describe a revolutionary imaging technology that compresses lamp light into a nanometer-sized spot. It holds that light at the end of a silver nanowire like a Hogwarts student practicing the “Lumos” spell, and uses it to reveal previously invisible details, including colors.

The advance, improving color-imaging resolution to an unprecedented 6 nanometer level, will help scientists see nanomaterials in enough detail to make them more useful in electronics and other applications.

“White” light from a tungsten lamp is focused into the tip of a silver nanowire to check the light scattering and absorption of a sample with high fidelity. Credit: Ma et. al, 2021

Ming Liu and Ruoxue Yan, associate professors in UC Riverside’s Marlan and Rosemary Bourns College of Engineering, developed this unique tool with a superfocusing technique developed by the team. The technique has been used in previous work to observe the vibration of molecular bonds at 1-nanometer spatial resolution without the need of any focusing lens.

In the new report, Liu and Yan modified the tool to measure signals spanning the whole visible wavelength range, which can be used to render the color and depict the electronic band structures of the object instead of only molecule vibrations. The tool squeezes the light from a tungsten lamp into a silver nanowire with near-zero scattering or reflection, where light is carried by the oscillation wave of free electrons at the silver surface.

This visualization shows the fiber-in-fiber-out process for optical spectroscopy measurement. Credit: Liu Group/UCR

The condensed light leaves the silver nanowire tip, which has a radius of just 5 nanometers, in a conical path, like the light beam from a flashlight. When the tip passes over an object, its influence on the beam shape and color is detected and recorded.

“It is like using your thumb to control the water spray from a hose,” Liu said, “You know how to get the desired spraying pattern by changing the thumb position, and likewise, in the experiment, we read the light pattern to retrieve the details of the object blocking the 5 nm-sized light nozzle.”

The light is then focused into a spectrometer, where it forms a tiny ring shape. By scanning the probe over an area and recording two spectra for each pixel, the researchers can formulate the absorption and scattering images with colors. The originally grayish carbon nanotubes receive their first color photograph, and an individual carbon nanotube now has the chance to exhibit its unique color.

“The atomically smooth sharp-tip silver nanowire and its nearly scatterless optical coupling and focusing is critical for the imaging,” Yan said. “Otherwise there would be intense stray light in the background that ruins the whole effort. “

The researchers expect that the new technology can be an important tool to help the semiconductor industry make uniform nanomaterials with consistent properties for use in electronic devices. The new full-color nano-imaging technique could also be used to improve understanding of catalysis, quantum optics, and nanoelectronics.

Reference: “6 nm super-resolution optical transmission and scattering spectroscopic imaging of carbon nanotubes using a nanometer-scale white light source” by Xuezhi Ma, Qiushi Liu, Ning Yu, Da Xu, Sanggon Kim, Zebin Liu, Kaili Jiang, Bryan M. Wong, Ruoxue Yan and Ming Liu, 25 November 2021, Nature Communications.DOI: 10.1038/s41467-021-27216-5

Liu, Yan, and Ma were joined in the research by Xuezhi Ma, who worked on the project as part of his doctoral research at UCR Riverside. Researchers also included UCR students Qiushi Liu, Ning Yu, Da Xu, Sanggon Kim; Zebin Liu and Kaili Jiang at Tsinghua University, and UCR professor Bryan Wong.